THE INSTANTANEOUS VALUES OF MAIN THERMODYNAMIC PARAMETERS AND POTENTIALS THAT ARE CHARACTERISTIC TO GIBBS THERMODYNAMIC MICROSTATES
The equations that combine the instantaneous values of main thermodynamic parameters and potentials (that are characteristic to Gibbs thermodynamic microstates) of the simplest gases and liquids were found. The maximum possible (limit) velocity of matter transfer and the four wave functions and derivatives from them, which can take with certain probability any arbitrary instantaneous values, are used as thermodynamic hidden parameters and variables in these equations. Such gases and liquids can gradually (evolutionally) quasi-equilibrium cool down with self-creation of stable gravitational fields due to electromagnetic interactions of their molecules. In those fields the local values of characteristic intensive parameter are saved in time and corresponding to it characteristic extensive parameter is the same in the whole space at the same time. The electro-magnetic nature of gravitational field in matter was justified. It was proved that hypothetical ideal matter (ideal gas, ideal liquid) in principal cannot self-create gravitational field due to the absence of electromagnetic interaction of its molecules. The dependencies of physical and other thermodynamic characteristics of matter on the hidden parameters and variables were examined.
Introduction
Internal energy U of real gases and liquids depends on many pairs of their intensive () and extensive () thermodynamic parameters. However, it can also be shown as a sum of internal energy of hypothetic ideal gas (liquid) and output of multiplication of resulting intensive () and extensive () thermodynamic parameters: , ,
where: , , . For gases: , is virial coefficients that depend on both temperature and individual gas properties [1], while is universal gas constant and is spatial thermodynamic parameter of matter, that does not vary in space at conditions of quasi-equilibrium ...
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